Odd how the same subject crops up in different lists & forums at the same time. Here's a post I wrote yesterday on the bevelheads list. Mind you, I'm quoting a 20 year post here.....
It's important to remember why stainless & chrome get these colours.
Nearly 20 years ago, Charles Falco (professor of optics at the Uni of
Arizona wrote a very good description of this. I had to dig into the you
Brit-Iron archives to find this:
"At 07:20 PM 8/26/98 -0400, you wrote:
> _> physics ruins restorations._
>
> _And sometimes new underwear._
>
> _One o' the early substances used for mirrors was quicksilver, which some_
> _folks call mercury. Tends to hang with a fella'_
>
> _Listen, while you're on this metal reflectivity kick, why don't you_
> _advise as to how come stainless, chromium, and other alloys change color_
> _(ok, change the color(s) they reflect) when they get hot as hell._
>
> _For example, when the exhaust pipes turn blue, what gives? Are we_
> _looking at some sort of compound between the chrome and stuff in the_
> _air, or what?_
The colors you're seeing on formerly-hot pipes are the result of an
interesting phenomenon: the destructive interference of specific
wavelengths/colors of light due to the formation of semi-transparent
oxides
that are of roughly comparable thickness to the wavelength. Note that
the
visible spectrum covers ~7000 Angstroms (red) ---> 4500 Angstroms
(violet),
and that 10,000 Angstroms = 1 micrometer = ~39 micro-inches. As a rough
approximation that's good enough for the present discussion, light with
a
wavelength that is approximately 4x the thickness of the oxide will be
absorbed by the film rather than be reflected. Such a film is called a
"quarter-wave anti-reflection coating." Thus, if an oxide is, say, ~1750
Angstroms thick, light near the red end of the spectrum (7000 A = 4 x
1750)
_won't_ be reflected, leaving mostly blue in the light bounced back to
our
eyes.
> _Howcome you (I) can remove discoloration of Stainless steel by_
> _mechanically gouging it off with a wire brush, but if I try to remove_
> _the bluing from chrome, the chrome comes off with it?_
The reason is the head of your stainless steel fastener is ~1/4" thick,
so
polishing away a few few micro-inches of oxide removes a negligible
amount
of the fastener. However, decorative chrome plating is only a few
micro-inches thick (~500-1000 Angstroms) to begin with, so by the time
it's
blue or yellow, all that's left of the plating is a transparent film of
chrome oxide anyway.
> _The exhaust bluing thread hasn't been around for a week or two, maybe_
> _this time it could present some science._
Amal jetting doesn't kill chrome, physics kills chrome.
Charles Falco"
---
Steve Borland
steve@it.dk