@kerinorton
Hey Tex, you just mentioned that retarded ign causes more fuel to burn in the pipes, causing bluing. Does that necessarily follow that a rich mixture will do the same.
When analyzing how ignition timing or mixture affects exhaust temperature, the key point to remember is that combustion of fuel requires a finite time. Fuel atoms, or more precisly fuel ions, must find and react with an oxygen ion before the exhaust valve opens, otherwise the reaction will take place in the exhaust system, raising exhaust temp. Advancing the timing provides more time for the reaction to occur in the cylinder, and retarding the timing less time.
Leaning a mixture reduces the mass of fuel relative to the mass of air in the cylinder. There are fewer available fuel ions and relatively more oxygen ions. The time required for fewer fuel ions to find and react with relatively more oxygen ions is therefore less, and virtually all the reaction occurs in the cylinder, producing useful work with minimum fuel consumption, higher cylinder temps and lower exhaust temp. Richening the mixture, increases the fuel mass and reduces, relatively, the oxygen ions. Thus the time required for the reaction to become essentially complete becomes longer with increasing richness, and may spill over into the exhaust system. Excessively rich mixtures lack the oxygen to burn, and the fuel goes out the tail pipe as raw hydrocarbons or as free carbon (black smoke).
When fuel combusts in the exhaust system, it results in a crackling and popping sound.
Slick