The exhaust valves run so hot, all the carbon burns off before it accumulates. The buildup could be a combination of rich fuel mixture AND oil, There is a period when the intake valve is beginning to open as the piston finishes the exhaust stroke when any oil present in the cylinder could be pushed back into the intake tract, so what you have could be a combination of all three of the named sources. The easiest way to check valve guide and stem wear is to disassemble the springs (looks like you've done that) and slide the valve back into the guide almost to the point of it hitting the seat, then try to wiggle it. If it moves very much at all, you likely need new guides at the least.