Powder coat can't be done in chrome, it's a type of paint. Metallic particles can be added, just like in regular spray painting. For certain parts, like exhaust pipes, plasma spray is a much better, more durable alternative.
Baked enamel was the old system for hard paint finishes. The paint went on and was baked hard in an oven. Powder coat puts the heat in the spray and binds the paint to the metal part. Plasma spray actually melts the metal in the spray and binds it to the part. Some alloy parts may not do well with plasma, since it goes on so hot. Certain alloys, especially thin stock parts may even be harmed by powder coating.