Make your own Ethanol Free Gasoline

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Have you guys ever seen anything like this?
I found it rather interesting and seems pretty easy to do.


MAKE YOUR OWN ETHANOL FREE GASOLINE

Ethanol is the scourge of owners of motorcycles, boats, and many other gasoline-operated vehicles and implements. E10 (10% ethanol) is pretty much the only available gasoline in most of the country now, with a few stations offering ethanol-free gas. And E15 (15% ethanol) is coming soon, recently approved by the EPA for 2001 and newer cars - even though the car manufacturers don't want it, and it is not approved for use by any motorcycle manufacturer either. You can thank the ethanol lobby for that.

"E15 won't be a problem - I'll just select my regular E10 on the pump," you may say. Well, there is a problem - the pipes and hose of the fuel pump contain about 3/4 gallon of whatever was last dispensed - and that could be E15. 3/4 gallon isn't much when you're pumping 15 gallons into your car, but when you're only pumping a few gallons into your bike, which doesn't like ethanol to begin with, 3/4 gallon makes a big difference!

What's the problem with ethanol? The biggest problem is phase separation. Like brake fluid, ethanol is hydroscopic, which means it bonds very easily to water. If there is moisture in the air (which there always is), the moisture bonds with the ethanol. The combination of water and ethanol is heavier than gasoline, so it falls to the bottom of the gas tank, where the pickup is. Let your bike sit for any length of time, particularly with a partially-full gas tank (because the air space left will contain moisture, and will expand and contract with heat, sucking in more moisture-laden air), and your tank will have a layer of water/ethanol mixture on the bottom. This is called phase separation. Guess what gets sucked into your engine the next time you start it? The water/ethanol mixture will burn in your engine, but it will burn much leaner and hotter, with the potential for serious engine damage as a result.

Ethanol is particularly corrosive to plastics, rubber, aluminum and fiberglass when compared to straight gasoline. If you have a vintage bike with a fiberglass tank, and are running E10 gasoline in it, the tank is likely swollen and on its way to failure as the ethanol breaks down the fiberglass. Many bikes have developed leaks and problems from swollen gaskets and failed rubber hoses and seals, all as a result of E10.

When E10 is allowed to sit for a long time, particularly somewhere where air can get in, like a normal vented gas tank, the volatile portion of the fuel will eventually evaporate. What's left is a milky goo. This goo eventually hardens into an amber solid, which then cracks into tiny pieces - heading directly into your carburetor to clog jets and cause failures.

Two stroke engines definitely have problems with E10: ethanol breaks down the lubrication provided by the fuel/oil mixture, leading to engine seizures!

So what is the solution? Well, you can check out the web site http://pure-gas.org to try to find a gas station near you that sells ethanol-free gas. Hint: many boat marinas sell ethanol-free gas, because with the added moisture in a boating environment, E10 plays havoc with boat engines.

Or...you can make your own ethanol-free gas. Yes, you heard me right! Make it yourself! I never even thought about doing this, until I read the excellent article "Removing Ethanol from E10 Fuel" by Dave Searle in the December 2012 issue of Motorcycle Consumer News - my absolute favorite magazine. If you haven't got a subscription to this magazine yet, stop reading this right now and go subscribe! I promise you won't be sorry. I've using a few pictures from Dave's article in this article.

So as you can guess, you don't actually make your own gasoline, you take regular E10 gasoline and remove the ethanol. Because ethanol boosts the octane in gasoline, I recommend you start with premium gas. Removing the ethanol from the premium will in the process lower the octane to the equivalent of regular gas. If you start with regular E10, you will need to add an octane booster, available at any auto store, or Wal-Mart.

So how do you remove the ethanol from E10? It's quite simple, actually - just add water! Remember, ethanol binds strongly to water. All you need to do is add some water to the gasoline, agitate to make sure it mixes well, then let it sit for a few minutes. The water will bond with the ethanol, and it will phase-separate out, falling to the bottom of the container.

How much water do you add? Well you can't add too much. If you don't add enough, then it won't remove all of the E10, and what E10 does bond with the water, will separate to the bottom of your container. If you add too much, the available ethanol will bond to the water, and the remaining water will separate to the bottom. You'll then have three layers: gasoline on top, ethanol/water in the middle, and water on the bottom:
Make your own Ethanol Free Gasoline

Three phase separation


In Dave's article, he used a cheap plastic separatory funnel with a small valve at the bottom, along with a 500cc cylinder for measuring the fuel and a 25cc burette for measuring water:
Make your own Ethanol Free Gasoline

Measuring instruments


Once filling his funnel with E10, adding water and letting it sit, the water/ethanol separated out, and could be drained using the valve:
Make your own Ethanol Free Gasoline

Separatory funnel


So how much water do you add? It depends on a few things, including the actual concentration of ethanol (which will vary - it's seldom exactly 10%), and ambient temperature. Dave's testing shows that the optimal amount of water is 2% by volume of the E10. That's 2.56 oz per gallon, or 12.8 ounces for a five-gallon gas can. Remember that extra water will simply separate out, so two cups (16 ounces) of water in a five-gallon gas can is safe. You should use distilled water only, to avoid leaving behind any minerals or other additives that your engine may not like (does fluoride keep your carburetors clean?).

The biggest problem - in what sort of container do you perform this procedure? Dave suggested a five-gallon glass or PET plastic jugs, like those that are found at http://www.midwestsupplies.com - fitted with stopcocks and vent tubes.

My suggestion is a bit simpler: Buy a regular five-gallon gas can:
Make your own Ethanol Free Gasoline



To the end of the spout, glue several inches of large, transparent PVC pipe:

Make your own Ethanol Free Gasoline


At the end of the PVC pipe, fasten a valve with a compression fitting:
Make your own Ethanol Free Gasoline

2-way-plastic-ball-valves-11605-2401007.jpg (11.56 KiB) Viewed 1542 times


Fill the can with E10, add two cups of distilled water, fasten the spout/pipe/valve, shake well, then turn the gas can upside down - fit it in a sawhorse or some other fixture so that the PVC pipe is pointing straight down. You want the absolute lowest point of the gas can to be the outlet for the spout, so that all of the heavier water and ethanol/water moves out the spout and then into the PVC tubing. Wait for the ethanol/water to separate out and drop down into the PVC (you'll see it), then open the valve slightly to drain out the ethanol/water. Once it's drained out, turn the gas can back upright - and you're done!

Make your own Ethanol Free Gasoline

Ethanol Extraction Rig


So do you want to do this every time you fill up your bike? Probably not. But it's certainly doable for small batches of gasoline for use in small engines (lawn mowers, weed trimmers, any two-stroke engine), to put in your bike just before putting it away for the winter (or for storage of any length of time), or for putting into devices that sit for long periods of time without being run - like backup generators.

I must give credit where due. This is reposted from a Honda Goldwing (GASP!) site called goldwingdocs.com
Read more: http://goldwingdocs.com/forum/viewtopic ... z2DqI5mMWk
 
It would be interesting to have this fuel analysed, and see what it now contained. ??

Since when you buy fuel containing ethanol, the ethanol is blended (dissolved) into the fuel, not just sloshing around on the bottom/top of the tank.

And I seem to recall from chemistry an eon ago, if you blend water and alcohol together, its almost physically impossible to get back 100% of it again, even with the most complicated chemistry - so is it the same once its been blended into the fuel ???
 
Don't confuse difficulty of making pure moonshine by separation of ethanol from water by distillation or chemical means from the above solubility separation. The amount of booze or water remaining after separation/titration is negligible. The only reason to bother is to store gas long term so water ain't dumped into tank later with the gas and for fiberglass tanks not coated well enough. If the boozed gas is consumed right fairly soon then its a non issue in our bikes components and not bad stuff to burn in chambers except for extra C02 and other pollutions to produce it. Ethanol may be a good cash crop again someday.
 
hobot said:
The amount of booze or water remaining after separation/titration is negligible.

How do you know that Steve - ever seen an analysis of the result ?
Otherwise, we are just guessing here. ???
 
Since it is ethanol, can't you boil it out and drink it (or sell it to compensate for the loss of gas) :?:

Jean
 
I've been finding a lot more places selling clear 92 octane, and I keep it on hand to top off with after rides. Almost forgot what real gas smelled like.
 
Jeandr said:
Since it is ethanol, can't you boil it out and drink it (or sell it to compensate for the loss of gas) :?:
Jean

What are you going to call it - gasoline flavored Vodka ?!!

Don't light a match while you are boiling it !!!!!!?????!!!!!
Gasoline has a VERY low flash point and a very high vapor pressure.

Distillation is none too efficient at separating substances with similar boiling points, 100% efficiency is something that just doesn't happen. Its near impossible to get anything faintly like pure alcohol by distillation alone, and even done chemically its usually tainted. Which is why hooch, moonshine, etc usually has a number of casualties every time they mention it on the news, for less than expert operators.... ?
 
Naw almost pure alcohol can be gotten "chemically" by adding desiccants that absorb water but does not react or remain in the alcohol so has nothing to do with the news reports of tainted 'shine, that only happens if the containers and tubes the mash is run through has lead solder joints, old patched radiators or Al or other toxic elements. Fumes are both toxic to breath long as well as explosive when confined but the extra octane allows more ignition advance torque before detonation. The better distillers use glass, copper, SS or ceramics as plastic adds yuky flavor so that stuff is usually added to fruit juices the women go for on hillbilly dances & dates. Had some rather rough trailer trash buddies tell me there's women that come down form the Mts to the local dance nights that are wild animals and so ugly nasty even moonshine can't make these dudes go back for more.
 
Tainted moonshine is also due to the unwelcome appearance of methanol - a lighter alcohol than ethanol. Difficult to detect*, and will persist even with multiple distillations.

*Cept when your fellow drinkers start keeling over, and can't be revived.
Rather more sudden than long-term metals poisoning....
 
All very well, have considered it myself but am fortunate enough to have 3 ethanol free gas stations within a few miles.

Bigest set-back, to my mind, is what the heck do you do with the water/Ethanol blend (probably a little gas in there too) that is left over?
 
Rohan there are the head heart and tails of distilling ethanol in batches and the better distillers do a simple 'fast' non-reflux column stripping run of the mash/wash first to get rid of the undesirable poisonous alcohols acetone short chain carbons and bump concentrate to 40's %-80 proof. Then with a reflux/fractionating column one can get 95% ethanol in one run so smooth it numbs plate on reaching middle of tongue w/o a hangover. Another way to de-water-alcohol gasoline is adding water to pull out the alcohol then let freeze then pour off the gasoline leaving the ice/ethanol mix behind, but needs rather low temps to do so. Fractionating crystallization is common way to concentrate ethanol in fermented juices especially near Arctic circle regions. Takes many cycles of freeze-thaw to end up with a core of 20's % ethanol to bore into and drain out. Spiked gas that has set in tank so water layer on bottom could be decanted off or syphoned off leaving the water/alcohol/gas mess behind.

Might be interesting to see if one could extract the ethanol out of the gas to drink, water wash gas then separate out then a stripping run then a refluxed run. Mash is only like 7-12% ethanol so in same ballpark moonshiners start with. There is a vacuum distillation that might do it all in one pass w/o washing out the gas first. Many make stills for fuel use ethanol like the first Fords intended.
 
hobot said:
Might be interesting to see if one could extract the ethanol out of the gas to drink, water wash gas then separate out then a stripping run then a refluxed run. Mash is only like 7-12% ethanol so in same ballpark moonshiners start with. There is a vacuum distillation that might do it all in one pass w/o washing out the gas first. Many make stills for fuel use ethanol like the first Fords intended.

Since there are warnings in labs about not drinking the washing ethanol - it still contains a trace of benzene, from the manufacturing, think I'll pass on drinking ethanol produced from washing down gasoline. The hydrogen OH bond in alcohols means it'll bond to stuff, and be almost impossible to separate 100% pure again...

Dunno where you got that recipe for moonshine - not from any moonshiners though ??!
Anything that'd strip methanol would also grab the ethanol ?
 
P.S. An obscure fact with that OH bond in alcohols is that if you add 100 gallons of alcohol (ethanol) to 100 gals of water, you only get 195 gal of product.

This causes enormous problems in accounting in distilleries.
(where did the 5 gal go ?).(its in the hydrogen bonds !)

And if distilled back again, you will never get back to 100 gal of water and 100 gal of alcohol, 100% pure from distillation just is not possible.
 
Rohan said:
And if distilled back again, you will never get back to 100 gal of water and 100 gal of alcohol, 100% pure from distillation just is not possible.

When I was in college, back in the '70s, I had a job working in the metallurgy lab, dispensing chemicals. They had USP ethanol in liter bottles, used as a solvent, for $2.00 apiece. 99.8% pure alcohol. I bought a few bottles for a frat party to add to the punch. I found out later that it contained trace amounts of stuff like benzene used to chase out the water. It is really hard to get more than 90% alcohol (180 proof), because it will suck water right out of the air. When this stuff was poured into the punch, if fizzed. A lot of girls got really sh**faced that night.

I got in a bit of trouble with my boss, but rebuilt his Holley and we were cool.
 
Thanx for the chemistry lesion on hydroxyl groups reacting to reduce volumes. I'm booze hangover sensitive so real cautious on some dark beers, wines and most any nameable liquor with a tax stamp on bottle. Real moonshine is the only thing I can get a comfortable numb buzz on w/o any hangover which is 'proof' enough for me its quite workable pure when stripped and triple thumped or tall reflux fraction column processed. Lab grade is mainly to avoid water so the benzene left overs etc that our livers don't like. I've tried the taxed stamped Georgia Moonshine sold in jars is rather weak and watered down slightly harsh tasting so takes like twice as much. The best moonshine I've had was in Belize when a smug native thought he'd goof with a tourist and challenged me to ID what was in his brown bagged jar. One whiff and I said surgar cane, having grown up in Fla with cane fields, duh. He lit up and shared it with me. Disappeared from perception about back of tongue to reappear as sense of nice heat released in mid section then head sort of floated off shoulders, so took another and sat down. Good Kickapoo Joy Juice is medicinal for pain and for bravery before Indian raids and dancing - singing in public.

I've mentioned peroxide rockets but to get H2O2 up to rocket fuel range 80's up, one must distill it from the water 30-50% H2O2 concentration and be real careful handling/storing.

Tag reflux or fractionating still here for the most efficient 95-96% producers.
http://homedistiller.org/

[video]http://www.youtube.com/watch?v=VhvLMeckcxY[/video]
 
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