No diagrams exist for the S model in the rear mudguard, oil tank, battery tray area that I have ever seen. The 69 spares book includes supplements for the S, R and 70 Roadster parts but no diagrams. Some of he part numbers in the book are questionable as well for the S, R and Roadster. As far as I have seen, there are 2 styles of oil tanks for the early bikes. One had the breather from the crankcase going into a spigot on a 'top hat' thing on top of the oil tank. Mine is like this. You can see the spigot here.
There is also a later style oil tank, I don't know when it changed. The spigot now is in the top of the main tank.
Here you can also see the 2 different type of rear mudguards, mine is on the left painted blue and mounts with a strap between the shock top bolts and a screw from the triangular horn mount off the battery tray. The mudguard on the right is a later S type and notice the flat spot on it. It mounts off a bracket (I don't have a picture) that mounts on the web between the frame below the shock top mounts I think. So again, there are 2 type of mudguards for the early S type.
I have fitted a later 71 style mudguard because I haven't gotten mine repaired and I haven't found a good replacement.
At the bottom of pages 20 and top of 21 in my album are pictures of the oil tank, and the battery tray that should show how that is assembled. In this picture, you can see the horn and the triangular mount, the bolt from the top right triangular piece goes through the battery tray lip, the triangular mount piece and then a nut, and also passes through the rear mudguard which has a small square reinforcement on it and then another nut to hold the mudguard down there also.
this may be a better picture of the rear mudguard strap between the shock tops and the center bolt from the battery tray that holds the fender also.
I hope this helps, if you have the correct parts it will go together, if not, it won't. I had to drill extra holes in the 71 rear guard to make it fit with my strap and the center hole from the battery tray. Seems like all the rear mudguards I see for the 69/70 are the ones with the flat spot on them.
Dave