Some comments on the two alloys from a Mahle designer.
McFarland: These two alloys are similar in many respects. In terms of overall strength the 2618 edges 4032 out by a small margin. Silicon content makes up the main effective difference with the 4032 alloy containing 12-13 percent silicon compared to 2618 alloy having 0.2 percent or less. Silicon reduces heat expansion, while being hard increases wear resistance. The decrease in expansion allows for tighter clearances, reduced wear on both the piston and bore, also resulting in quieter operation. The hard silicon element greatly helps to increase the number of heat cycles the piston can endure before ring grooves and skirts start to distort. This makes the 4032 alloy well suited for a wide range of applications from street performance to upper level sportsman racing. The 2618 alloy is more malleable, allowing it to flex and move under extreme loads further and more frequently before reaching the point of fracture. This gives the 2618 alloy a greater resistance to the shock loads of detonation. The compromise is that the alloy softens at a much faster rate, allowing the piston to distort more rapidly. This makes the 2618 alloy best suited for extreme-duty race applications where the engine will be serviced on a regular schedule. Mahle uses the 2618 alloy for extreme-duty applications or those that have a high likelihood for experiencing aggressive and or frequent detonation. Due to the increased wear resistance and longevity characteristics of the 4032 alloy, Mahle uses this alloy on a wider scale.
Ken